The whole movie centers on how Merida not wanting to be married and not wanting a love interest, and the movie instead focuses on her relationship with her mother. She certainly, I believe, deserves a spot on the top 10 list.
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Top 10 Disney Protagonists Without a Love Interest
#2
Suggested by
TheMichaelCityMaker
Moana - Moana (2016)
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#3
Suggested by
TheMichaelCityMaker
Winnie the Pooh - 'Winnie the Pooh' franchise (1966-)
It makes sense Joy has no love interests. The five emotions we follow throughout the story are more like co-workers than anything else. Honestly, I'm not sure that any of them are really friends other than (by the end of the movie) Joy and Sadness.
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#9
Suggested by
TheMichaelCityMaker
James P. 'Sulley' Sullivan - 'Monsters, Inc.' franchise (2001-)